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3 Buli Fußball - 2020/2021: 10. Spieltag
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The ending you know- here I am in Louise Hill. You see, I am also a world-hopper, as well as a wizard. Unbelievable, right?
I came to this world a great many years ago, before this town was ever named Louise Hill. Back then, I animated all manner of things, and a good deal quicker than you've been managing.
I once animated a creatures so large its wings spanned the distance from here to Aviar Cove. It grew from a great oak tree.
But over time I no longer have it in me to animate such magnificent creatures, hence why I have needed your help.
Thank you for being a fantastic assistant. Hopefully, by observing your ability to animate turnips, I can find a way to regain my own incredible abilities.
PS: Haha, you believed that? It was a fun story though, wasn't it? I definitely had fun coming up with it, maybe I should try creative writing.
Stop by soon, I need more data on Turniplings. Listen here—stop trying to sabotage my experiments. You can't deny it! I've caught you lurking around my laboratory, not to mention all the time you've deliberately brought me the wrong items.
I should know better than to ask for your help by now, but you insistently turn up again and again.
Surely, just once, you'll surprise me and do something right. But I would rather you never try again.
Was my last warning not enough? This time, I have a threat: stay away unless you're willing to sit down for an entire day and let me observe your animating magic.
Threats, warnings Misshapen turnips! Scrawny, ugly turnips! See if I don't find a way to have you hopping to another world where you can't annoy me to death.
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Hello world hopper, How are my experiments going you ask? Hi world hopper, How's the world traveling? Oh hello, You have proven yourself time and again to be a resourceful and useful assistant, it's been a surprise to me really.
How are you..? Assistant of the Year, You really have been so helpful to me since you first came into this world. Fondly, Buli PS: Haha, you believed that?
Hello there world hopper, I was just walking by the post when I realized, it's your birthday. The stability and volatility of the butane resulting from such deprotonation reactions is convenient, but can also be a problem for large-scale reactions because of the volume of a flammable gas produced.
The kinetic basicity of n -BuLi is affected by the solvent or cosolvent. Such additives can also aid in the isolation of the lithiated product, a famous example of which is dilithioferrocene.
Schlosser's base is a superbase produced by treating butyllithium with potassium tert-butoxide. It is kinetically more reactive than butyllithium and is often used to accomplish difficult metalations.
The butoxide anion complexes the lithium and effectively produces butylpotassium, which is more reactive than the corresponding lithium reagent. An example of the use of n-butyllithium as a base is the addition of an amine to methyl carbonate to form a methyl carbamate , where n-butyllithium serves to deprotonate the amine:.
Butyllithium reacts with some organic bromides and iodides in an exchange reaction to form the corresponding organolithium derivative.
The reaction usually fails with organic chlorides and fluorides:. This reaction is useful for preparation of several types of RLi compounds, particularly aryl lithium and some vinyl lithium reagents.
The utility of this method is significantly limited, however, by the presence in the reaction mixture of n-BuBr or n-BuI, which can react with the RLi reagent formed, and by competing dehydrohalogenation reactions, in which n-BuLi serves as a base:.
These side reaction are significantly less important for RI than for RBr, since the iodine-lithium exchange is several orders of magnitude faster than the bromine-lithium exchange.
For these reasons, aryl, vinyl and primary alkyl iodides are the preferred substrates, and t-BuLi rather than n-BuLi is usually used, since the formed t-BuI is immediately destroyed by the t-BuLi in a dehydrohalogenation reaction thus requiring 2 equiv of t-BuLi.
Alternatively, vinyl lithium reagents can be generated by direct reaction of the vinyl halide e. A related family of reactions are the transmetalations , wherein two organometallic compounds exchange their metals.
Many examples of such reactions involve Li exchange with Sn :. The tin-lithium exchange reactions have one major advantage over the halogen-lithium exchanges for the preparation of organolithium reagents, in that the product tin compounds C 4 H 9 SnMe 3 in the example above are much less reactive towards lithium reagents than are the halide products of the corresponding halogen-lithium exchanges C 4 H 9 Br or C 4 H 9 Cl.
Other metals and metalloids which undergo such exchange reactions are organic compounds of mercury , selenium , and tellurium. Organolithium reagents, including n -BuLi are used in synthesis of specific aldehydes and ketones.
One such synthetic pathway is the reaction of an organolithium reagent with disubstituted amides :. This process, which consumes butyllithium to generate butane, induces a reverse cycloaddition to give enolate of acetaldehyde and ethylene.
Alkyl-lithium compounds are stored under inert gas to prevent loss of activity and for reasons of safety. This is an exergonic reaction.
If oxygen is present, butane is going to react with oxygen and start fire. From Wikipedia, the free encyclopedia.
Redirected from BuLi. Organolithium reagent. NBL, BuLi, 1-lithiobutane. CAS Number. Interactive image. PubChem CID. Chemical formula.
Solubility in water. Molecular shape. Dipole moment. Related organolithium reagents. Main article: Organolithium reagent.
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